Equivalent Concept

IMPORTANT

Equivalent Concept: Overview

This topic covers concepts, such as, Normality, Equivalent Weight, Valency Factor for Disproportionating Species & Valency Factor for Comproportionating Species etc.

Important Questions on Equivalent Concept

EASY
IMPORTANT

What is the  [OH]  in the final solution prepared by mixing 20.0 mL of 0.050 M HCl with 30.0 mL of 0.10  M Ba(OH)2 ?

MEDIUM
IMPORTANT

The equivalent weight of   N a 2 S 2 O 3 .5 H 2 OandKBr O 3  In the following reactions would be:

  (i)2 S 2 O 3 2 + I 2 S 4 O 6 2 +2 I (ii)Br O 3 +6 H + +6 e B r +3 H 2 O

MEDIUM
IMPORTANT

The density of copper is  8.94 g ml1.  The number of coulombs needed to plate an area   10cm×10cm  to a thickness  102 cm using CuSO4 solution as electrolyte are:

MEDIUM
IMPORTANT

Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of the metal is

EASY
IMPORTANT

KMnO4 reacts with H2O2 in an acidic medium. The number of moles of oxygen produced per mole of KMnO4 is;

MEDIUM
IMPORTANT

20 mL solution of 0.1 M ferrous sulphate was completely oxidised using a suitable oxidising agent. What is the number of electrons exchanged?

MEDIUM
IMPORTANT

What are the number of moles of KMnO4 that will be needed to react with one mole of SO32-ion  in acidic solution?

MEDIUM
IMPORTANT

Molten AlCl3 is electrolysed with a current of 0.5 A to produce 27.0 g Al.

How many litres of Cl2 at NTP were produced?(Report the answer in 2 significant numbers)

MEDIUM
IMPORTANT

Find the equivalent weight of H3PO4, in the reaction,

Ca(OH)2+H3PO4=CaHPO4+2H2O.

HARD
IMPORTANT

How many gram of H2S will react with 63.2 g of KMnO4 to produce K2SO4 and MnO2? Give answer after rounding off to the nearest integer.

MEDIUM
IMPORTANT

A certain amount of metal, whose equivalent weight is 28, displaces 0.7 litre of hydrogen measured at NTP from an acid. Calculate the weight of the metal.

Give your answer to the nearest integer value after multiplying with 4.

MEDIUM
IMPORTANT

If 6×10-3 mole of K2Cr2O7 reacts completely with 9×10-3 mole of Xn+ to give XO3- and Cr3+, then, the value of n is

MEDIUM
IMPORTANT

The equivalent weight of an element is 4. Its chloride has a vapour density 59.25. Then the valency of the element is

EASY
IMPORTANT

Arsenic forms two oxides, one of which contains 65.2% and the other 75.7% of the element. Hence, equivalent masses of arsenic are in the ratio :

EASY
IMPORTANT

Explain Equivalent mass of element.

HARD
IMPORTANT

Carbon forms two oxides, namely carbon monoxide and carbon dioxide. The equivalent mass of which element remains constant? 

HARD
IMPORTANT

Volume V1 mL of 0.1M K2Cr2O7 is needed for complete oxidation of 0.678g N2H4 in acidic medium. The volume in mL of 0.3 M KMnO4 needed for same oxidation in the acidic medium will be

MEDIUM
IMPORTANT

In alkaline medium, KMnO4 reacts as follows (Atomic weights K=39.09, Mn=54.94, O=16.00)

2KMnO4+2KOH2K2MnO4 +H2O+[O]

Hence, its equivalent weight is

HARD
IMPORTANT

Equivalent weight of chlorine molecule in the equation is : 3Cl2+ 6NaOH 5NaCl+ NaClO3+3H2O

MEDIUM
IMPORTANT

An aqueous solution of 6.3 g of oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH required to completely neutralize 10 mL of this solution is